List of Publications

Professor Ilan Marek – List of Publications

1) Ilan Marek, Pierre Mangeney, Alex Alexakis* and Jean-F. Normant
Are Allenes formed from Propargylic thers Through a Syn or Anti-Displacement?
Tetrahedron Lett. 27, 5499-5502 (1986)

2) Alex Alexakis*, Pierre Mangeney, Abdellaziz Ghribi, Ilan Marek, Richard Sedrani, Christophe Guir and Jean-F. Normant
Chiral Acetals in Enantio-and Diastereoselective Substitution or Elimination Reactions
Pure & Appl.Chem. 60, 49-56 (1988)

3) Alex Alexakis* Ilan Marek, Pierre Mangeney, Jean-F. Normant
Diastereoselective Synthesis of -Allenic Alcohols from Propargylic Epoxides
Tetrahedron. Lett. 30, 2387-2390 (1989)

4) Alex Alexakis* Ilan Marek, Pierre Mangeney, Jean-F. Normant
Copper-Catalyzed Reductive Metallation of a Propargylic Epoxide to an Allenyl Lithium Reagent
Tetrahedron. Lett. 30, 2391-2392 (1989)

5) Jean-P. Declercq* and Ilan Marek
Structure of 1,3,5-triallyl-4,6-diphenyl-1,3,5-triazacyclohexan-2-one
Acta. Cryst., C46, 1168-1170 (1990)

6) Alex Alexakis* Ilan Marek, Pierre Mangeney, Jean-F. Normant
Mechanistic Aspects on the Formation of Chiral Allenes From propargylic Ethers and Organocopper Reagents
J. Am. Chem. Soc. 112, 8042-8047 (1990)

7) Alex Alexakis*, Ilan Marek, Pierre Mangeney and Jean-F. Normant
Diastereoselective Syn or Anti Opening of Propargylic Epoxides. Synthesis of -allenic Alcohols
Tetrahedron 47, 1677-1696 (1991)

8) Ilan Marek*, Alex Alexakis and Jean-F. Normant
A Highly Efficient Synthesis of (Z)--iodo Allylic Alcohols
Tetrahedron Lett. 32, 5329-5332 (1991)

9) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Acyclic Stereocontrol Through the Metalla-Claisen Rearrangement. Part I
Tetrahedron Lett. 32, 5969-5972 (1991)

10) Ilan Marek* and Jean-F. Normant,
Acyclic Stereocontrol through the Metalla-Claisen Rearrangement. Part II
Tetrahedron Lett. 32, 5973-5976 (1991)

11) Ilan Marek*, Alex Alexakis and Jean-F. Normant*
-tributylstannyl--metallated Acrolein: A Versatile Synthon
Tetrahedron Lett. 32, 6337-6340 (1991)

12) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Iodocyclisation of Olefinic t-butyl Ethers: An Easy Stereocontrolled Synthesis of Cis-Substituted Tetrahydrofurans
Tetrahedron Lett. 33, 1747-1748 (1992)

13) Ilan Marek, Alex Alexakis*, Pierre Mangeney and Jean-F. Normant
Synthese d’Alcoxyallenes Chiraux par Carbocupration d’Acetals Propargyliques.  Etude de Leur Reactivite à l’egard d’Organocuprates
Bull. Soc. Chem. Fr. 129, 171-190 (1992)

14) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Acyclic Stereocontrol Via Organogembismetallic Reagents. Part III
Synlett 633-634 (1992)

15) Jean-F. Normant, Ilan Marek and Jean-Michel Lefrancois
Organobismetallic Zinc Reagents: Their Preparation and Use in Diastereoselective Reactions
Pure and Appl. Chem. 64, 1857-1864 (1992)

16) Alex Alexakis*, Pierre Mangeney, Ilan Marek, Francoise Rose-Munch, Eric Rose, Assia Semra and Francis Robert
Resolution and Asymmetric Synthesis of Ortho-Substituted (Benzaldehyde) Tricarbonylchromium Complexes
J. Am. Chem. Soc. 114, 8288-8290 (1992)

17) Dov Beruben, Ilan Marek*, Lydie Labaudiniere and Jean-F. Normant*
Cyclic Stereocontrol Via Organobismetallic Reagents.  Part V.  Diastereoselective Synthesis of Substituted Cyclopropyl Zinc Reagents by the Metalla-Claisen Reaction
Tetrahedron Lett. 34, 2303-2306 (1993)

18) Christophe Meyer, Ilan Marek* and Jean-F. Normant*
Carbocyclisation of Functionnalized Zinc Organometallics
Synlett 266-268 (1993)

19) Christophe Meyer, Ilan Marek* and Jean-F. Normant*
(E)-or (Z)--iodoacrolein: A Novel Versatile Synthon
Synlett 386-388 (1993)

20) Fabrice Chemla*, Ilan Marek and Jean-F. Normant*
Selective Monoalkylation of Organogembismetallics Via an Intramolecular Nucleophilic Substitution
Synlett 665-666 (1993)

21) Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Intramolecular Carbometallation of Secondary Organozinc Reagents
Tetrahedron Lett.34, 6053-6056 (1993)

22) Dov Beruben, Ilan Marek*, Jean-F. Normant* and Nicole Platzer
Cyclic Steocontrol Via Organobismetallic Reagents.  Part VI.  Stereodefined Substituted Cyclopropyl Zinc Reagents
Tetrahedron Lett. 34, 7575-7578 (1993)

23) Sophie Klein, Ilan Marek* and Jean-F. Normant*
Carbolithiation of Cinnamyldialkylamines. Stereochemistry of the Li to Zn transmetalation and Configurational Stability of Benzylic Organozinc Halides
J. Org. Chem. 59, 2925-2926 (1994)

24) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Diastereoselective Carbometalation of Vinyl Metals
J. Org. Chem. 59, 4154-6166 (1994)

25) Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Intramolecular Carbometallation of Organozinc Reagents
Tetrahedron 50, 11665-11692 (1994)

26) Christophe Meyer, Ilan Marek*, Jean-F. Normant and Nicole Platzer*
Carbocyclization of -acetylenic Propargylic Zinc Reagents
Tetrahedron Lett. 35, 5645-5648 (1994)

27) Isabelle Creton, Ilan Marek*, Denis Brasseur, Jean-Luc Jestin and Jean-F. Normant*
Phenylthioacetylene as a Source of Stereodefined Trisubstituted Alkenes
Tetrahedron Lett. 35, 6873-6876 (1994)

28) Ilan Marek*, Jean-Michel Lefrancois and Jean-F. Normant*
Diastereoselective Carbometalation of -Heterosubstituted Vinylmetals
Bull. Soc. Chim. Fr. 131, 910-918 (1994)

29) Christophe Meyer, Ilan Marek*, Gilles Courtemanche and Jean-F. Normant*
Intramolecular Metallo-Ene-Allene Reactions. A New Carbocycles Synthesis
J. Org. Chem. 60, 863-871 (1995)

30) Edwige Lorthiois, Ilan Marek*, Christophe Meyer and Jean-F. Normant*
Zinca-En-Allene Cyclization.  Synthesis of Substituted Tetrahydrofurans
Tetrahedron Lett. 36, 1263-1266 (1995)

31) Dov Beruben, Ilan Marek*, Jean-F. Normant and Nicole Platzer
Stereodefined Substituted Cyclopropyl Zinc Reagents from Gembismetallics
J. Org. Chem. 60, 2488-2501 (1995)

32) Ilan Marek*, Dov Beruben and Jean-F. Normant*
Metal-Alkene -Chelation: A Stereodirecting Effect in Allylzincation Reactions and in Zinc Mediated Cyclopropanations
Tetrahedron Lett. 36, 3695-3698 (1995)

33) Fan Wang, Jie Tang, Lydie Labaudiniere, Ilan Marek* and Jean-F. Normant*
Diastereoselective Reactions of Gembismetallic Derivatives
Synlett 723-7251 (1995)

34) Sophie Klein, Ilan Marek*, Jean Francois Poisson and Jean-F. Normant*
Asymmetric Carbolithiation of Cinnamyl Derivatives in the Presence of (-) Sparteine
J. Am. Chem. Soc. 117, 8853-8854 (1995)

35) Isabelle Creton, Ilan Marek* and Jean-F. Normant*
Stereoselective Synthesis of Polysubstituted Olefins Via the Formation of 1,1-Bimetalloalkenes
Tetrahedron Lett. 36, 7451-7454 (1995)

36) Denis Brasseur, Ilan Marek* and Jean-F. Normant*
Diastereoselective Synthesis of Heterosubstituted Organogembismetallic Reagents.  Application to a New Propargylmetalation Reaction of Vinyl Metals
Tetrahedron 52, 7235-7250 (1996)

37) Christophe Meyer, Ilan Marek* and Jean-F. Normant*
Stereoselective Synthesis of Linear and Angular Triquinanes Skeletons via the Zinca-Ene Allene Reactions
Tetrahedron Lett. 37, 857-860 (1996)

38) Anja Bahr, Ilan Marek* and Jean-F. Normant*
Diastereoselective Carbometalation of -Mono and --Disubstituted Z Vinyl Metals
Tetrahedron Lett. 37,5873-5876 (1996)

39) Edwige Lorthiois, Ilan Marek*, Christophe Meyer and Jean-F. Normant*
Intermolecular Carbolithiation of Silylated Enynes
Tetrahedron Lett. 37, 6689-6692 (1996)

40) Edwige Lorthiois, Ilan Marek* and Jean-F. Normant*
Intramolecular Carbolithiation of Silylated Enynes
Tetrahedron Lett. 37, 6693-6694 (1996)

41) Isabelle Creton, Ilan Marek* and Jean-F. Normant*
Synthesis of Polysubstituted Stereodefined Olefins via the Reactivity of sp2, Organogembismetallics
Synthesis 1499-1508 (1996)

42) Synthesis and Reactivity of sp3 Geminated Organobismetallics
Ilan Marek* and Jean-F. Normant
Chem. Rev. 96, 3241-3267 (1996)

43) Ilan Marek, Christophe Meyer and Jean-F. Normant
A Simple and Convenient Method for the Preparation of (Z) or (E)--Iodo Allylics Alcohols and (Z)--Iodo Acrolein
Org. Synth. 74, 194-204 (1997)

44) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Zinca-en-allene and Zinc-enolate Cyclization. Towards the Synthesis of Polysubstituted Pyrrolidines
Tetrahedron Lett. 1997, 38, 89-92 (1997)

45) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Zinca-ene-allene Cyclizations. A way to Substituted Tetrahydrofurans or Pyrrolidines
Bull. Soc. Chim. Fr. 134, 333-341 (1997)

46) Stephanie Norsikian, Ilan Marek*, Jean-Francois Poisson, Jean-F. Normant*
Enantioselective Carbolithiation of Cinnamyl Acetals. New Access to Chiral disubstituted Cyclopropanes
J. Org. Chem. 62, 4898-4899 (1997)

47) Stephanie Norsikian, Ilan Marek*, Jean-F. Normant*
Enantioselective Carbolithiation of -alkylated Styrene
Tetrahedron Lett. 38, 7523-7526 (1997)

48) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Amino-Zinc-Enolate carbocyclization reactions. New Access to Polysubstituted Piperidines Derivatives
J. Org. Chem. 64, 566-574 (1998)

49) Edwige Lorthiois, Ilan Marek*, Jean-F. Normant*
Diastereoselective and Enantioselective Intramolecular Amino-Zinc-Enolate Carbometalation Reactions. A New Polysubstituted Pyrrolidines Synthesis
J. Org. Chem. 63, 2442-2450 (1998)

50) Benoit Folleas, Ilan Marek*, Jean-F. Normant* and Laurent Saint Jalmes
Fluoroform: An Efficient Precursor for the Trifluoromethylation of Carbonyl Compounds
Tetrahedron Lett. 39, 2973-2976 (1998)

51) Denis Brasseur, Hadi Rezaei, Alain Fuxa, Alex Alexakis, Pierre Mangeney, Ilan Marek*, Jean F. Normant*
First Diastereoselective carbometalation Of Chiral Vinyl Metals
Tetrahedron Lett. 39, 4821-4824 (1998)

52) Denis Brasseur, Ilan Marek*, Jean F. Normant*
Diastereoselective Carbometalation of Chiral Vinyl Metals
C. R. Acad. Sci. Paris, t.1, Serie II c 621-625 (1998)

53)  Ilan Marek, Jean-F Normant
Carbometalation Reactions in Transition Metals for Fine Chemicals and Organic Synthesis,
Eds. Bolm, C., Beller, C. Wiley-VCH, 514-522 (1998)

54) Ilan Marek, Jean-F Normant
Carbometallation Reactions in Metal-Catalyzed Cross-Coupling Reactions
Eds Stang, P.J., Diederich, F. Wiley-VCH, 271-337 (1998)

55)  Ilan Marek, Jean-F Normant
Preparation and Reaction of 1,n-bimetallic Reagents in Practical Approach in Organozinc Chemistry
Ed . Knochel, P. Oxford University Press, 119-137 (1998)

56) Isabelle Creton, Hadi Rezaei, Ilan Marek*, Jean F Normant*.
First Transfer of Chirality in the Fritsch- Buttenberg-Wiechell Rearrangement, via Zinc Carbenoids : A migration with Retention of Configuration
Tetrahedron Lett. 40, 1899-1902 (1999)

57) Nathalie Bremand, Ilan Marek*, Jean F. Normant*
Regioselective addition of nbutyllithium on secondary cinnamyl amides Michael versus contra-Michael process
Tetrahedron Lett. 40, 3379-3382 (1999)

58) Nathalie Bremand, Ilan Marek*, Jean F. Normant*
Diastereoselective contra-Michael addition of (-)-sparteine/organolithium complexes to secondary chiral cinnamyl amides
Tetrahedron Lett. 40, 3383-3386 (1999)

59) Stephanie Norsikian, Ilan Marek*, Sophie Klein, Jean-Francois Poisson, Jean F. Normant*
Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes. Configurational Stability of Benzylic Organozinc Halides
Chem. Eur. J. 5, 2055 (1999)

60) Ilan Marek, Peter R. Schreiner, Jean F. Normant
The Allyl Zincation of Vinyl Metals. A Computational Study
Org. Lett. 1, 929-931 (1999)

61) Salvatore Avolio, Christophe Malan, Ilan Marek, Paul Knochel
Preparation and Reaction of Functionalized Magnesium Carbenoids
Synlett 11, 1820-1822 (1999)

62) Claudia Averbuj, Julia Kaftanov, Ilan Marek
First Synthesis of Metallated Titanacyclopropenes
Synlett 11, 1939-1941 (1999)

63) Lionel Aufauvre, Paul Knochel, Ilan Marek
A New Approach towards the Synthesis of sp3 1,1-diiodoalkanes
Chem. Commun, 2207-2208 (1999)

64) Arindam Chakraborty, Ilan Marek
Iodine Transfer cyclization mediated by DIBAL-H/THF
Chem. Commun.2375-2376 (1999)

65) Enantioselective Carbometalation of unactivated Olefins
Ilan Marek
J. Chem. Soc. Perkin Trans. 1, 535-544 (1999)

66) Benoit Folleas, Ilan Marek, Jean F. Normant
Fluoroform: An efficient precursor for the trifluoromethylation of aldehydes
Tetrahedron 56, 275-283 (2000)

67) Arindam Chakraborty and Ilan Marek*
New one-pot Synthesis of -Iodoalkyne
Synthetic Comm. 30, 1895-1901 (2000)

68) Julia Kaftanov, Natalia Vais-Morlender, Claudia Averbuj, Annie Liard, Ilan Marek
Synthesis and reactivity of Polymetallated Olefins and Functionalized Metallo-Alkynes
Polyhedron 19, 563-566 (2000) Invited paper

69) Edwige Lorthiois, Jean Normant, Ilan Marek
Novel Stereoselective and Enantioselective Synthesis of Heterocyclic Compounds by Anionic Method
Actual. Chim.(3), 60-61 (2000) Invited paper

70) Natalia Vais-Morlender, Julia Kaftanov and Ilan Marek
First Synthesis and reactivity of functionalized alkynyl titanium derivatives.
Synthesis, 917-920 (2000) Invited paper

71) Annie Liard, Ilan Marek
Stereoselective Preparation of E Vinyl Zirconium Derivatives from E or Z Enol Ether
J. Org. Chem. 7518-7220, 65, (2000)

72) Jos Varghese, Paul Knochel, Ilan Marek
New Allene Synthesis via Carbocupration- Zinc Carbenoid Homologation and -elimination
Org. Lett.2, 2849-2852 (2000)

73) Natalia Vais-Morlender, Nicka Solodovnikova, Ilan Marek
Carbometalation of unactivated alkynes via low valent titanium derivatives.
Chem. Commun. 1849-1850 (2000)

74) Synthesis and Reactivity of sp2 Geminated Organobismetallics
Ilan Marek
Chem. Rev. 100, 2887-2900 (2000)

75) Amal Shibli, Jos P. Varghese, Paul Knochel, Ilan Marek
Improved preparation of secondary zinc iodides by 1,2-migration of sp3 carbenoids
Synlett 818-820 (2001)

76) Hadi Rezaei, Ilan Marek, Jean F. Normant
Diastereoselective Carbozincation of Propargylic Amines
Tetrahedron 57, 2477-2483 (2001)

77) Annie Liard, Helena Chechik, Shahera Farhat, Natalia Morlender-Vais, Claudia Averbuj, Ilan Marek
Oxidative Addition--elimination: A New Method for the preparation of organometallic compounds
J. Organomet. Chem. 624, 26-33, (2001)

78) Ilan Marek
Preface for a special issue of the Journal of Organometallic Chemistry dedicated to Prof. Jean F. Normant
J. Organomet. Chem. 624, 1-3, (2001)

79) Viet Anh Vu, Ilan Marek, Kurt Polborn, Paul Knochel
Preparation of New Functionalized Cyclopropylmagnesium Reagents
Angew. Chem. Int. Ed. 41, 351-352, (2002); Angew. Chem. (2002), 114, 361-362

80) Shahera Farhat and Ilan Marek
From Vinyl Sulfides, Sulfoxides and Sulfones to Transition Metal Complexes
Angew. Chem. Int. Ed. 41, 1410-1413, (2002); Angew. Chem. (2002), 114, 1468-1471

81) Swapan Majumdar, Armin de Meijere and Ilan Marek
Catalytic Asymmetric and Stereoselective Synthesis of Vinyl Cyclopropanes
Synlett 423-426, (2002)

82) Stefan Wiedemann, Ilan Marek, Armin de Meijere
Functionalized Aminocyclopropanes from Functionalized Organozinc Compounds and N,N Dialkylcarboxamides.
Synlett 879-882, (2002)

83) Eike Hupe, Ilan Marek and Paul Knochel
Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers and Acyclic Molecules
Org. Lett.  4, 2861-2863, (2002)

84) Carbocupration-Zinc Carbenoids Homologation and -Elimination Reactions for a New Synthesis of Allenes. Applications to a New Synthesis of Chiral Allenes via Deracemization of Sp3 Organometallic Derivatives
Jos P. Varghese, Irena Zouev, Lionel Aufauvre, Paul Knochel and Ilan Marek
Eur. J. Org. Chem. 4151-4158, (2002)

85)  New Methods for the Preparation of Sp2 Organometallic derivatives
Nicka Chinkov, Helena Chechik, Swapan Majumbar, Annie Liard and Ilan Marek
Synthesis, Invited review, 2473-2483, (2002)

86) New Preparation of Stereodefined -Unsaturated Ketones by Carbomagnesiation of -allenyl ketone
Nicka Chinkov, Natalia Morlender-Vais, Ilan Marek
Tetrahedron lett. 43, 6009-6010, (2002)

87) New Approach to the Stereoselective Synthesis of Metallated Dienes via an Isomerization-Elimination Sequence
Nicka Chinkov, Swapan Majumdar, Ilan Marek
J. Am. Chem. Soc. 124, 10282-10283, (2002)

88)  Sp3 Organozinc Carbenoid Homologation in Organic Synthesis
Ilan Marek
Tetrahedron Report, 58, 9463-9475, (2002)

89) Leila Motiei, Ilan Marek, Hugo Gottlieb, Vered Marks and Jean-Paul (Moshe) Lellouche
Reaction of Allylzirconocene Compounds with Isolated or In Situ Generated 5Pentadienyl Fe(CO)3 /Fe(CO)2 PPh3(+1) Cations.
Tetrahedron Lett. 44, 5909-5912, (2003)

90) Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Compounds
Viet Anh Vu, Ilan Marek, Paul Knochel
Synthesis, 1797-1802, (2003)

91)  Synthesis and Reactivity of Geminated Organobismetallic Derivatives
Ilan Marek
Actualite Chimique, special issue on the Present and future in Chemistry, 17-24, (2003) (Invited contribution)

92) Four-Component Reactions for a New Diastereo- and Enantioselective Synthesis of Chiral Quaternary Centers.
Genia Sklute, Deborah Amsallem, Amal Shibli, Jos P. Varghese and Ilan Marek
J. Am. Chem. Soc. 125, 11776-11777, (2003)

93) Stereoselective Preparation of Dienyl Zirconocene Complexes via a Tandem Allylic C-H bond Activation-Elimination Sequence
Nicka Chinkov, Swapan Majumdar and Ilan Marek
J. Am. Chem. Soc. 125, 13258-13264, (2003)

94) Regio- and Stereoselective Synthesis of Novel E-Alkenyl Carbamate via Carbocupration Reaction
Helena Chechik and Ilan Marek
Org. Lett. (2003) 5, 5087-5089

95) From Vinyl Sulfides, Sulfoxides and Sulfones to Vinyl Zirconocene Derivatives
Shahera Farhat, Irena Zouev and Ilan Marek
Tetrahedron (Special issue on Zirconium Chemistry by invitation only), (2004), 60, 1329-1337

96) -Sulfinyl Carbanions as A New Source of Olefins
Adi Abramovitch, Jos P. Varghese, Ilan Marek
Org. Lett. (2004), 6, 621-623

97) Diastereoselective Reduction of Cyclopropenylcarbinol: new Access to Anti-Cyclopropylcarbinol Derivatives
Elinor Zohar and Ilan Marek
Org. Lett. (2004), 6, 341-343

98) Convenient Access to 2-(Trialkylstannyl)cyclopropylamines and Their Application in Palladium-Catalyzed cross-Coupling Reactions
Stefan Wiedemann, Karsten Rauch, Andrei Savchenko, Ilan Marek, Armin de Meijere
Eur. J. Org. Chem. (2004) 631-635

99) Stereoselective Preparation of Deuteriated Dienes by Ring Fragmentation of Metallated Cyclopropylcarbinols
Elinor Zohar, Mirit Ram and Ilan Marek
Synlett (2004) 1288-1290

100) Nicka Chinkov, Daniella Tene and Ilan Marek
Carbometalation Reaction
inMetal-Catalyzed Cross-Coupling Reactions- second edition
Eds Diederich, F.; de Meijere, A. Wiley-VCH, (2004), 395-478

101) Daniella Tene and Ilan Marek
Carbometallation Reaction
inTransition Metals for Fine Chemicals and Organic Synthesi-second edition
Eds C. Bolm , M. Beller, Wiley-VCH, (2004), 563-573

102) Frederic Leroux, Manfred Schlosser, Elinor Zohar and Ilan Marek
The Preparation of Organolithium Compounds and Derivatives
inThe Chemistry of Organolithium Compounds
Eds Rappoport, Z.; Marek, I., John Wiley & Sons, Chichester, (2004), 435-493

103) Nicka Chinkov and Ilan Marek
Stereoselective Synthesis of Dienyl Zirconocenes Complexes
Topic in Organometallic Chemistry
Volume: New Aspects of Zirconium Containing Organic Compounds
Springer Verlag, (2004), 133-166

104) New Regio-, Stereo-, Diastereo-, and enantioselective One-Pot Reactions Mediated by Organometallic Derivatives
Nicka Chinkov, Genia Sklute, Helena Chechik, Adi Abramovitch, Deborah Amsallem, Jos, P. Varghese, Swapan Majumbar and Ilan Marek
Pure and Applied Chem. (2004) 76, 517-535

105) Stereoselective Synthesis and Reactivity of Dienyl Zirconocene
Nicka Chinkov, Swapan Majumbar and Ilan Marek
Practical Synthetic ProceduresSynthesis, (2004), 2411-2417

106) Ambiphilic Zinc Carbenoid as a New Tool for Multicomponent Condensation Reactions
Ilan Marek
Isr. Chem.Soc. (2004), 16, 22-32

107) Synthesis of Chiral Methylenecyclopropanes Derivatives
Elinor Zohar, Amnon Stanger and Ilan Marek
Synlett (2005), 2239-2241

108) Regiocontrolled Carbometallation Reactions of Ynamides
Helena Chechik-Lankin, Shulamit Livshin and Ilan Marek
Synlett (2005), 2098-2100

109) Ilan Marek and Helena Chechik-Lankin
Functionalized Organozirconium and Titanium in Organic Synthesis
In Functionalized Organometallic Derivatives
Ed. P. Knochel, Wiley-VCH, Weinheim, 2005, 503-540

110) Preparation and Synthetic Transformation of Alkenyl Carbamate into Vinyl Zirconocene Derivatives
Helena Chechik-Lankin and Ilan Marek
Synthesis (2005), 3311-3318

111) Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and Sulfoxide/Magnesium Exchange Reactions
Felix Kopp, Genia Sklute, Kurt Polborn, Ilan Marek and Paul Knochel
Org. Lett. (2005), 7, 3789-3791

112) Special issue of Tetrahedron Symposium-in-Print on Multicomponent Reactions
Ilan Marek
Tetrahedron, (2005), 61, 11309-11519. Guest Editors

113) New Tandem Zn-Promoted Brook Rearrangement/Ene-Allene carbocyclization Reactions
Rozalia Unger, Theodore Cohen and Ilan Marek
Org. Lett. (2005), 7, 5313-5316

114) Unsaturated Fatty Alcohol Derivatives as a New Source of Substituted Allylzirconocenes
Nicka Chinkov, Anat Levin and Ilan Marek
Angew. Chem., Int. Ed., (2006), 45, 465-468; Angew. Chem. (2006), 118, 479-482.

115) Chiral Cyclopropenylcarbinols as a New Source of Chiral Alkylidenecyclopropane Derivatives
Samah Simaan, Ahmad Masarwa, Philippe Bertus and Ilan Marek
Angew. Chem., Int. Ed., (2006), 45, 3963-3965; Angew. Chem. (2006), 118, 4067-4069.

116) Multicomponent Approach for the Creation of Chiral Quaternary Centers in the Carbonyl Allylation Reactions
Genia Sklute and Ilan Marek
J. Am. Chem. Soc. (2006), 128, 4642-4649

117) A Zirconium Promenade; A Efficient Tool in organic Synthesis
Ilan Marek, Nicka Chinkov and Anat Levin
Synlett (account), 501-514 (2006)

118) Regio- and Stereoselective Copper-Catalyzed Carbozincation of Alkynylsulfoximines
Genia Sklute, Carsten Bolm and Ilan Marek
Org. Lett. (2007), 9, 1259-1261.

119) Stereodivergent Carbometalation Reactions of Cyclopropenylcarbinols Derivatives
Samah Simaan and Ilan Marek
Org. Lett. (2007), 9, 2569-2571

120) Creation of Chiral Quaternary Stereocenters in the Carbonyl Allylation Reactions
Ilan Marek and Genia Sklute
Chem. Commun. (Feature article), (2007), 43,1683-1691

121) Enantiomerically Enriched Cyclopropene Derivatives: Versatile Building Blocks in Asymmetric Synthesis
Ilan Marek, Samah Simaan, Ahmad Masarwa
Angew. Chem. Int. Ed. (2007), 46, 7364-7376; Angew. Chem. (2007), 119, 7508-7520; (Corrigenda Angew. Chem. Int. Ed. (2008), 47, 1982; Angew. Chem. (2008), 120, 2008).

122) An Efficient, Facile and general Stereoselective Preparation of Heterosubstituted Alkylidenecyclopropanes
Ahmad Masarwa, Amnon Stanger and Ilan Marek
Angew. Chem. Int. Ed. (2007), 46, 8039-8042; Angew. Chem. (2007), 119, 8185-8188.

123) Diastereodivergent Synthesis of Enantiomerically Pure Homoallylic Amine Derivatives Containing Quaternary Carbon Stereocenters
Goren Kolodney, Genia Sklute, Sylvie Perrone, Paul Knochel and Ilan Marek
Angew. Chem. Int. Ed. (2007), 46, 9291-9294; Angew. Chem. (2007), 119, 9451-9454.

124) Intramolecular Carbozincation of Unactivated Alkenes Occurs Through a Zinc Radical Transfer Mechanism
Theodore Cohen, Heather Gibney, Roman Ivanov, Edmund A.-H. Yeh, Ilan Marek and Dennis P. Curran
J. Am. Chem. Soc. (2007), 129, 15405-15409

125) Synthesis of Sulfoximidoyl-Substituted Triazoles by Huisgen 1,3-Dipolar Cycloaddition
Bernhard Fuger, Genia Sklute, Ilan Marek, Gae Young Bolm, Carsten Bolm
Synlett, (2008), 116-118

126) Cyclopropenyllithiums as a New Source of 1,1-Bismetalated Cyclopropyl Derivatives
Anat Levin and Ilan Marek
Chem. Commun. (2008), 4300

127)A shift in Retrosynthetic Paradigm (Concept article)
Ilan Marek
Chem. Eur. J. (2008), 14, 7460-7468

128) Convergent Preparation of Enantiomerically Pure Polyalkylated Cyclopropane Derivatives
Adi Abramovitch, Louis Fensterbank, Max Malacria and Ilan Marek
Angew. Chem. Int. Ed. (2008) 47, 6865-6868

129) Zinc Homologation-Elimination Reaction of Sulfinyl Carbanions as a New Route to Olefins
Adi Abramovitch and Ilan Marek
Eur. J. Org. Chem. (2008) 4924-4931

131) Stereoselective Synthesis of Metalated Cyclobutane Derivatives
Einav Tsoglin, Helena Chechik, Guy Karseboom, Nicka Chinkov, Amnon Stanger and Ilan Marek
Advanced Synthesis and Catalysis (2009), 351, 1005-1008

132) Copper-catalyzed Hydride Transfer Towards the Formation of Alkylidenecyclopropane Derivatives
Samah Simaan and Ilan Marek
Chem. Commun (2009), 292-294

133) Diastereo- and Enantioselective Zinc ene-allene Carbocyclization
Rozalia Unger, Fritz Weisser, Nicka Chinkov, Amnon Stanger, Theodore Cohen and and Ilan Marek
Org. Lett. (2009), 11, 1853-1856

134) Enantioselective Construction of all-Carbon Quaternary Stereogenic Carbons in Aldol Reactions
Jaya P. Das, Helena Chechik and Ilan Marek
Nature Chemistry, (2009), 1, 128-132
[Highlighted in Angew. Chem. Int. Ed. 2009, 48, 7971 (D. C. Koester, D. B. Werz)]

135)Tandem Zn-Brook rearrangement/Ene-Allene Carbocyclization
Rozalia Unger, Theodore Cohen, Ilan Marek
Eur. J. Org. Chem. (2009), 1749-1756

136) The Basics of Zinc Activation (Perspectives)
Ilan Marek
Science, (2009), 326, 673-674

137) Cyclopropenylcarbinol Derivatives: New Versatile Intermediates in Organic Synthesis. Application to the Formation of Enantiomerically Pure Alkylidenecyclopropane Derivatives.
Samah Simaan, Ahmad Masarwa, Elinor Zohar, Amnon Stanger, Philippe Bertus, Ilan Marek
Chem. Eur. J. (2009), 15, 8449-8464

138) Preface for a special issue of Chemistry, A European Journal dedicated to Yitzhak Apeloig
Miri Karni, Ilan Marek, Sason Shaik
Chem. Eur. J. (2009), 15, 8340-8343

139) Enantioselective preparation of enantiomerically Pure Cyclobutene derivatives
Ahmad Masarwa, Alois Fürstner and Ilan Marek
Chem. Commun (2009), 5760-5762

140) Metal-Catalyzed Ring-Opening of Alkylidenecyclopropanes as a New Approach to the Preparation of Enantiomerically Pure all-Carbon Quaternary Stereocenters
Samah Simaan, Alex F. G. Golberg, Stephane Rosset and Ilan Marek
Chem. Eur. J(2010), 16, 774.

141) Regiodivergent Carbometalation Reactions of Ynol Ether Derivatives
Anat Levin, Ahmad Basheer and Ilan Marek
Synlett (2010), 329.

142) The Superiority of Properly Prepared Lithium 1-N,N-Dimethylaminonaphthalenide (LDMAN) over Other Aromatic Radical-anions for the Generation of Organolithiums by Reductive Lithiation
Roman Ivanov, Ilan Marek and Theodore Cohen
Tetrahedron Lett.(2010), 51, 174-176

143) Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A new Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons
Samah Simaan and Ilan Marek
J. Am. Chem. Soc. (2010), 132, 4066-4067

144) Highly Diastereoselective Preparation of Homoallylic Alcohols Containing Two Contiguous Quaternary Stereocenters in Acyclic Systems from Simple Terminal Alkynes
Bishnu Dutta, Noga Gilboa and Ilan Marek
J. Am. Chem. Soc. (2010), 132, 5588-5589

145) Diastereo- and Enantioselective Intramolecular Carbometalation Reaction
Rozalia Unger, Theodore Cohen and Ilan Marek
Tetrahedron (2010), 66, 4874-4881

146) Selectivity in Metal-Catalyzed Carbon-Carbon Bond Cleavage of Alkylidenecyclopropanes
Ahmad Masarwa and Ilan Marek
Chem. Eur. J. (2010), 16, 9712-9721

147) Regioselective Carbon-Carbon Bond Cleavage in the Oxidation of Cyclopropenylcarbinols
Ahmad Basheer, Massaki Mishima and Ilan Marek
Org. Lett (2011), 13, 4076-4079.

148) Recent Advances in Carbocupration of -heterosubstituted alkynes
Ahmad Basheer and Ilan Marek
Beilstein J. Org. Chem. (2010), 6, No. 77.doi:10.3762/bjoc.6.77

149) Enantioselective Synthesisof all-Carbon Quaternary Stereogenic Centers in Acyclic Systems
Jaya P. Das and Ilan Marek
Chem. Commun. (Feature article) (2011), 47, 4593-4623.

150) Carbometalation of Carbon-Carbon Double Bonds in Stereoselective Carbometalations of Carbon-Carbon Double Bonds.
Ilan Marek* and Ahmad Basheer
Stereoselective Synthesis 1 in Science of Synthesis Ed: J. G. de Vries, (2011), 325-408.

151) Axial Preferences in Allylation via the Zimmerman-Traxler Transition State
Noga Gilboa, Hoa Wang, Ken N. Houk and Ilan Marek
Chem. Eur. J. (2011), 17, 8000-8004

152) Conjugate Additions to Alkylidene Bis-sulfoxides
Frank Brebion, Guillaume Vincent, Saloua Chelli, Ophelie Kwasnieski, Francisco Najera, Benedicte Delouvrie, Ilan Marek, Etienne Derat, Jean-Philippe Goddard, Max Malacria, Louis Fensterbank
Chem. Asian J. (2011), 6, 1825-1833

153) Combined Carbometalation–Zinc Homologation–Allylation Reactions as a New Approach for Alkoxyallylation of Aldehyde
Tom Mejuch, Mark Botoshansky, and Ilan Marek
Org. Lett. (2011), 13, 3604-3607

154) Efficient Brønsted Acid Catalyzed Hydrations and Hydroaminations of (Dicyclopropylmethylene)cyclopropane
Lutz Ackermann,Sergei I. Kozhushkov,Dmitry S. Yufit,Ilan Marek
Synlett, (2011), 1515-1518

155) Convergent Diastereoselective Preparation of Adjacent Quaternary Stereocenters in an Acyclic System
Tom Mejuch, Bishnu Dutta, Mark Botoshansky and Ilan Marek
Organic and Biomolecular Chemistry (2012), 10, 5803-5806 (Special issue for 10th Birthday)

156)Forming All-Carbon Quaternary Stereogenic Centres in Acyclic Systems from Alkynes
Yury Minko, Morgane Pasco, Luckas Lercher, Mark Botoshansky, Ilan Marek
Nature, (2012), 490, 522

157) Alkenyl Zinc reagents in Cross-Coupling Reactions
In Cross-Coupling and Heck-Type Reactions 1 − C-C Cross Coupling Using Organometallic Partners
Tom Mejuch and Ilan Marek
Science of Synthesis, (2012), 765-794.

158) Carboxylate-Assisted Ruthenium(II)-Catalyzed Hydroarylations of Unactivated Alkenes via C–H Cleavage
Marvin Schinkel, Ilan Marek and Lutz Ackermann
Angew. Chem., Int. Ed. (2013), 52, 3977-3980.

159) New Advances in Bis(sulfoxides) Chemistry
Sophie Beauvière, Franck Brebion, Saloua Chelli, Bénédicte Delouvrié, Catherine Gomez, Ophélie Kwasnieski, Rocio Martinez Mallorquin, Francisco Najera, Guillaume Vincent, Maxime R. Vitale, Etienne Derat, Ilan Marek, Max Malacria, Jean-Philippe Goddard, Louis Fensterbank
Phosphorus Silicon & Related, (2013), 188, 367-376

160) Carboxylate-assisted Ruthenium(II)-Catalyzed C-H Arylation of 5-Aryl Tetrazoles: Step-Economical Access to Valsartan
Emelyne Diers, N. Y. Phani Kumar, Tom Mejuch, Ilan Marek, Lutz Ackermann
Tetrahedron, (2013), 69, 4445-4453.

161) Carbon-Carbon Bond Activation en Route to the Formation of all-Carbon Quaternary Stereogenic Centers in Acyclic System
Pierre-Olivier Delaye, Dorian Didier, Ilan Marek
Angew. Chem. Int. Ed. (2013), 52, 5333-5337

162) The Renaissance of Zinc Carbenoid in Stereoselective Synthesis in Acyclic systems
Morgane Pasco, Noga Gilboa, Tom Mejuch, Ilan Marek
Organometallics, (2013), 32, 942-950.

163) Regio- and Stereoselective Carbometallation Reactions of N-Alkynyl-Amides and Sulfonamides
Yury Minko, Morgane Pasco Helena Chechik and Ilan Marek
Beilstein J. Org. Chem. (2013), 9, 526-532.

164) Axial Preferences in Allylation Reactions via the Zimmerman – Traxler Transition State
Tom Mejuch, Noga Gilboa, Eric Gayon, Hao Wang, K. H. Houk, Ilan Marek
Acc. Chem. Res. (2013), 46, 1659-1669.

165) Stereodefined Trisubstituted Enolates as a Unique Entry to All-Carbon Quaternary Stereogenic Centres in Acyclic Systems
Yury Minko, Morgane Pasco, Lukas Lecher, Ilan Marek
Nature Protocols, (2013), 4, 749-754.

166) Carboxylate-Assistance for Catalyzed Hydroarylations of Methylenecyclopropanes
Marvin Schinkel, Jan Wallbaum, Sergei I. Kozhushkov, Ilan Marek, Lutz Ackermann
Org. Lett. (2013), 15, 4482-4484.

167) A One-Pot Zinc-promoted Asymmetric Alkynylation/Brook-Type Rearrangement/Ene-Allene Cyclization: Highly Selective Formation of Three New bonds and two Stereocenters in Acyclic Systems
Polina Smirnov, Jomon Mathew, Anne Nijs, Einat Katan, Miriam Karni, Carsten Bolm, Yitzhak Apeloig, Ilan Marek
Angew. Chem. Int. Ed. (2013), 52, 13717-13721.

168) Carbometalation Reactions
Ilan Marek and Yury Minko
inMetal-Catalyzed Cross-Coupling Reactions and More- First edition
Eds de Meijere, A.,Oestreich, M., Brase, S. Wiley-VCH, (2014), 769-882.

169) Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes
Dorian Didier, Pierre-Olivier Delaye, Marwan Simaan, Biana Island, Guillaume Eppe, Hendrik Eijsberg, Amir Kleiner, Paul Knochel, Ilan Marek
Chem. Eur. J. (2014), 20, 1038-1048

170)Merging Allylic C-H Activation and Selective C-C Bond Activation
Ahmad Masarwa, Dorian Didier, Tamar Zabrodsky, Marvin Schinkel, Lutz Ackermann and Ilan Marek
Nature (2014) 505, 199-203
Highlighted in C&EN, 2013, December 16
Highlited in Nature Chemistry, 2014, 6, 86

171) Carbometalation Reactions
Dorian Didier, Ilan Marek
In Copper-catalyzed Asymmetric Synthesis, First Edition.
Edited by Alexandre Alexakis, Norbert Krause and S. Woodward. Wiley-VCH, (2014), 267-282.

172) Advances in Carbolithiation
Yury Minko and Ilan Marek
In Lithium Compounds in organic Synthesis: From Fundamentals to Applications, First Edition.
Edited by Renzo Luisi and Vito Capriati. Wiley-VCH (2014), 329-350

173) Oxenoids in Organic Synthesis
Yury Minko and Ilan Marek
Organic and Biomolecular Chemistry (2014), 12, 1535-1546.

174) Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents
Zhi-Liang Shen, Zhihua Peng, Chun-Ming Yang, Julian Helberg, Peter Mayer, Ilan Marek and Paul Knochel
Org. Lett. (2014), 16, 956-959

175) All-Carbon Quaternary Stereogenic Centers in Acyclic System through the Creation of Several C-C bonds per Chemical Steps
Ilan Marek, Yury Minko, Morgane Pasco, Tom Mejuch, Noga Gilboa, Helena Chechik, Jaya P. Das
J. Am. Chem. Soc. (2014), 136, 2682-2694

176) Chemistry in Israel−at a Crossroads? (Editorial)
Ilan Marek
Angew. Chem. Int. Ed. (2014), 53, 3754-3755

177) Isoxazole-Embedded Allylic Zinc Reagent for the Diastereoselective Preparation of Highly Functionalized Aldol-Type derivatives Bearing a Stereocontrolled Quaternary Center
Lydia Klier, Coura R. Diene, Manuel Schikinger, Albrecht Metzger, Andrea J. Wagner, Konstantin Karaghiosoff, Ilan Marek and Paul Knochel
Chem.-Eur. J. (2014), 20, 20, 14096-14101

178) Stereodefined Acyclic Trisubstituted Metal Enolates Towards the Asymmetric Formation of Quaternary Carbon Stereocentres
Yury Minko, Ilan Marek
Chem. Comm. (2014), 50, 12597- 12611

179) Formation of Three New Bonds and Two Stereocenters in Acyclic Systems by Zinc-Mediated Asymmetric Alkynylation of Acylsilanes, Brook Rearrangement and Ene-Allene Carbocyclization Reactions
Polina Smirnov, Einat Katan, Jomon Mathew, Arseni Kostenko, Miriam Karni, Anne Nijs, Carsten Bolm, Yitzhak Apeloig, Ilan Marek
J. Org. Chem. (special issue “Mechanisms in Metal-Based Organic Chemistry “), (2014), 79,12122-12135.
180) Electrophilic Amination: The Case of Nitrenoids
Pavel Starkov, Timothy F. Jamison, Ilan Marek
Chem. Eur. J (2015), 14, 5278-5300.

181) Selective Carbon-Carbon Bond Cleavage for the Stereoselective Synthesis of Acyclic Systems
Ilan Marek, Ahmad Masarwa, Pierre-Olivier Delaye, Markus Leibeling
Angew. Chem. Int. Ed. (2015), 54, 414-429.

182) Gold and Silver-Catalyzed Intramolecular Cyclizations of Indolylcyclopropenes for the Divergent Synthesis of Azepinoindoles and Spiroindoline Piperidines
Peng-Long Zhu, Zhen Zhang, Xiang-Yiang Tang, Ilan Marek, Min Shi
ChemCatChem (2015), 7, 595-600.

183) Remote Functionalization of Hydrocarbons with Reversibility Enhanced Stereocontrol
Alexandre Vasseur, Lionel Perrin, Odile Eisenstein, Ilan Marek
Chemical Sciences (2015), 6, 2770-2776.

184) Cyclopropene Derivatives  as a New Entry to Enantioenriched Cyclopropanol and n-Butenal Possessing Quaternary Carbon Stereocenters
Marwan Simaan, Pierre-Olivier Delaye, Min Shi and Ilan Marek
Angew. Chem. Int. Ed. (2015), 54, 12345-12348. DOI: 10.1002/anie.201412440
185) Formation of Several Carbon-Carbon Bonds in Acyclic Systems
Guillaume Eppe Dorian Didier andIlan Marek
Chemical Reviews, (2015), 105, 9175-9206. DOI: 10.1021/cr500715t

186) Probing the Limits of NMR and VCD Spectroscopies in the Stereochemical Assignement of Chiral 2H6-Neopentane
Ahmad Masarwa, Dennis Gerbig, Liron Oskar, Aharon Loewenstein, Hans Peter Reisenauer, Philipe Lesot, Peter R. Schreiner, Ilan Marek
Angew. Chem. Int. Ed. (2015) 54, 13106-13109.DOI: 10.1002/anie.201505349

187) Forming Stereogenic Centers in Acyclic Systems from Alkynes
Rozane Vabre, Biana Island, Claudia J. Diehl, Peter R. Schreiner, Ilan Marek
Angew. Chem. Int. Ed. (2015) 54, 9996-999.

188) Gold(I)-Catalyzed Cycloisomerization of Vinylidenecyclopropane-enes via Carbene or non-Carbene Processes
De-Yao Li, Yin Wei, Ilan Marek, Xiang-Ying Tang, Min Shi
Chemical Science (2015), 6, 5519-5525.

189) Stereodefined Acyclic Trisubstituted Silyl Enol Ethers Towards The Asymmetric Formation of Aldol Products Possessing Quaternary Carbon Stereocenters
Zackaria Nairoukh and Ilan Marek
Angew. Chem. Int. Ed. (2015), 54, 14933-14937.DOI: 10.1002/anie.201507209

190) Quinazoline-based tricyclic compounds that regulate programmed cell death, induce neuronal differentiation, and are curative in animal models for excitoxicity and hereditary brain disease
A. Vainshtein, L. Veenman, A. Shterenberg, S. Singh, A. Masarwa, B. Dutta, B. Island, E. Tsoglin, E. Levin, S. Leschiner, I. Maniv, L. Pe’er, I. Otradnov, S. Zubedat, S. Mizrachi, A. Weizman, A. Avital, I. Marek, M. Gavish
Cell Death Discovery, (2015), 1, 15027; DOI: 10.1038/cddiscovery.201527

191) The Scientific Bridge: Fifty Years of Germany-Israel Diplomatic Relations
Helmut Schwarz, Itamar Willner and Ilan Marek
Angew. Chem. Int. Ed. (2015), 51, 12182-12183

192) Carbozincation of alkynes and alkenes
Genia Skulte, Hannah Cavender and Ilan Marek
Org. React. (2015) 87, 507-763.

193) Asymmetric Copper-Catalyzed Carbozincation of Cyclopropenes en route to the Formation of Diastereo- and Enantiomerically Enriched Polysubstituted Cyclopropanes
Daniel S. Müller and Ilan Marek
J. Am. Chem. Soc. (2015), 137, 15414-15417

194) Merging allylic C-H bond activation and C-C bond cleavage en route to the formation of quaternary carbon stereocenter in acyclic systems
Alexandre Vasseur and Ilan Marek
Nature Protocols (2016), Accepted for Publication

195)Copper mediated carbometalation reactions
D. S. Müllerand I. Marek,
Chem. Soc. Rev. (2016) Accepted for Publication.

196) Remote Functionalization
Alexandre Vasseur, Jeffrey Bruffaerts, Ilan Marek
Nature Chem. (2016) 8, 209-219

197) Stereoselective Formation of Trisubstituted Ketone Enolates
Elvira Haimov, Zackaria Nairoukh, Alexandre Shterenberg, Tiran Herkowitch, Timothy F. Jamison, Ilan Marek
Angew. Chem. Int. Ed. (2016), 55, 5517-5520.

198) Brook Rearrangement as a Trigger for Ring-Openingstrained Carbocycles
Fa-Guang Zhang, Guillaume Eppe and Ilan Marek
Angew. Chem. Int. Ed. (2016), 52, 714-718.

199) Diastereodivergent Combined Carbometalation − Zinc Homologation – C-C Fragmentation Reaction as an Efficient Tool to Prepare Acyclic Allylic Quaternary Carbon Stereocenters
Sudipta Raha Roy, Dorian Didier, Amir Kleiner and Ilan Marek
Chemical Science (2016), In Press. DOI: 10.1039/C6SC02191C

200) Preparation and Reactivity of Acyclic Chiral Allylzinc Species via a Zn-Brook Rearrangement
Markus Leibelling, Khriesto A. Shurrush, Veronika Werner, Lionel Perrin, Ilan Marek
Angew. Chem. Int. Ed. (2016), 55, 6057-6061.

201) Oxidation of bis-Sulfinyl Carbanion as the Pivot of Ionic/Radical Tandem Reactions
Guillaume Vincent, Saloua Chelli,  Rocio Martinez Mallorquin, Adi Abramovitch, Sophie Beauvière, Catherine Gomez, Franck Brebion, Ilan Marek, Max Malacria,Jean Philippe Goddardand Louis Fensterbank
Compte Rendu Academie des Sciences (2016), In press. DOI: doi:10.1016/j.crci.2015.11.0

202) Formation of Carbon Quaternary Stereogenic Center in Acyclic Systems via a Sequence of Carbometalation − Intramolecular Cyclization − Silicon Activation
Maya Preshel-Zlatsin, Fa-Guang Zhang, Guillaume Eppe, Ilan Marek
Synthesis (2016), In Press

203) Diastereoselective Carbometalation of Cyclobutenes
Sudipto Raha Roy, Hendrik Eijsberg, Jeffrey Bruffaerts, Ilan Marek
Chemical Science (2016), Submitted